Unexpected formation of aryl-cyanides during the oxidative decomposition of aryl-cyanocuprates. Transfer of a non-transferable group?

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Unexpected formation of aryl-cyanides during the oxidative decomposition of aryl-cyanocuprates. Transfer of a non-transferable group?
 
Kronenburg, Claudia M.P; Amijs, Catelijne H.M; Wijkens, Peter; Jastrzebski, Johann T.B.H; Van Koten, Gerard
(2002) Tetrahedron Letters, volume 43, issue 6, pp. 1113 - 1115
(Article)
Abstract
Oxidative decomposition of cyanocuprates of the type CuLi(CN)Ar (Ar = [C6H4(CH2NMe2)-2]-, 1a) or type CuLi2(CN)Ar2(1b) shows the unexpected formation of aryl-cyanides in up to 30% yield. © 2002 Elsevier Science Ltd. All rights reserved.
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Keywords: copper derivative, cyanide, article, decomposition, gas chromatography, ion transport, mass spectrometry, oxidation
DOI: https://doi.org/10.1016/S0040-4039(01)02337-1
ISSN: 0040-4039
Publisher: Elsevier
(Peer reviewed)
 
 
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