Abstract
Complexes of the type [MCl{2}XR'{3}]{2}R-dim (M = Pd or Pt; XR'{3} = arsine or phosphine) are formed in almost quantitative yield in the reactions of [MCl{2}XR'{3}]{2} with @a-diimine (11 molar ratio Pt-dimer/R-dim). An X-ray study of [PtCl{2}PBu{3}]{2}t-Bu-dim [Z = 2, a = 11.4540(11), b = 16.1169(7), c = 12.9202(12) @9
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