Abstract
Trinuclear [{(Ph{2}P){3}CH}Ag{3}(O{2}CR'){3}], dinuclear [{(Ph{2}P){2}CHR}Ag{2}(O{2}CR'){2}], [{(Ph{2}P){2}CHR}{2}Ag{2}](BF{4}){2} and (Rh{2}(Cl)(CO){2}{(Ph{2}P){2}CHMe}{2}][RhCl{2}(CO){2}], and mononuclear (Rh{(Ph{2}P){2}CHR}{2}](BF{4}), (Rh{(Ph{2}P){2}CHR}{2}HCl](BF{4}), d [Rh{(Ph{2}P){2}CHR}{2}Cl(HgCl)](BF{4}) and (Rh{(Ph{2}P){2}CHR}{2}O{2}](BF{4}) (R = H,Me) were synthesized from the phosphines tris(diphenylphosphino)methane ((Ph{2}P){3}CH), bis(diphenylphosphino)methane ((Ph{2}P){2}CH{2}) and 1,1-bis(diphenylphosphino)ethane ((Ph{2}P){2}CHMe). The }1{H, }1{}3{C and }3{}1{P NMR spectra were investigated and for the mononuclear rhodium compounds compared with their 1,2-bis(diphenylphosphino)ethane and
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