Ruthenium carbonyl 1,4-diaza-1,3-butadiene (R-DAB) reaction sequence: Reversible CO addition to a trinuclear species without rupture of a metal-metal bond. Molecular structure of [1,4-dicyclohexyl-1,4-diaza-1,3-butadiene]nonacarbonyltriruthenium, Ru3(CO)9(c-Hx-DAB). A unique 50e trinuclear compound with two elongated Ru-Ru bonds

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