Ruthenium carbonyl 1,4-diaza-1,3-butadiene (R-DAB) complexes. Reactivity of Ru3(CO)8(R-DAB) toward diazomethane. Addition of a methylene fragment to a trinuclear species with concomitant rupture of a single Ru-Ru bond. Molecular structure of octacarbonyl(1,4-dineopentyl-1,4-diaza-1,3-butadiene)(m-methylene)triruthenium: (m-CH2Ru3(CO)8 (neo-Pen-DAB)

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Ruthenium carbonyl 1,4-diaza-1,3-butadiene (R-DAB) complexes. Reactivity of Ru3(CO)8(R-DAB) toward diazomethane. Addition of a methylene fragment to a trinuclear species with concomitant rupture of a single Ru-Ru bond. Molecular structure of octacarbonyl(1,4-dineopentyl-1,4-diaza-1,3-butadiene)(m-methylene)triruthenium: (m-CH2Ru3(CO)8 (neo-Pen-DAB)
 
Koten, G. van; Keijsper, J.; Polm, L.H.; Vrieze, K.; Goubitz, K.; Stam, C.H.
(1985) Organometallics, volume 4, issue 10, pp. 1876 - 1881
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ISSN: 0276-7333
Publisher: American Chemical Society
 
 
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