Ruthenium carbonyl 1,4-diaza-1,3-butadiene (R-DAB) complexes. Reactivity of Ru2(CO)6(R-DAB) towards hetero-allenes L (L = carbodiimide, sulphine), resulting in C-C bond formation. X-ray molecular structure of Ru2(CO)5(t-BuN=CHC(H)(Nt-Bu)-C(N-p-Tol)=N-p-Tol) and of Ru2(CO)5(i-PrN=CHC(H)(Ni-Pr)C(S)C12H8)

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