Abstract
The concept of fluorous biphasic separation has been applied in the recycling of rhodium-based catalysts for the hydrosilylation of 1-alkenes and fluorinated 1-alkenes by following two approaches. Hydrosilylation of 1-hexene using various silanes and fluorous versions of Wilkinson's catalyst [RhCl{P(C6H4-4-SiMe2Rf)3}3] (1; Rf = CH2CH2C6F13) or [RhCl{P(C6H4-4-SiMe(Rf)2)3}3] (2; Rf = CH2CH2C8F17)
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