Abstract
Reaction of sulfurdiimines RN@?S@?NR and the isoelectronic and structurally analogous sulfinylanilines RN@?S@?O with [Me{3}Al]{2} gave the complexes [Me{2}Al{RNS(Me)NR} ]{2}(R @? 4-MeC{6}H{4}, 4- ClC{6}H{4}, 2, 6-Me{2}C{6}H{3}) and [Me{2}Al{RNS(Me)O}]{2}(R = Me, C{6}H{5}, 4-MeC{6}H{4}, 4-ClC{6}H{4}, 2,6-Me{2}C{6}H{3} and 2,4,6-Me{3}C{6}H{2}) in which the S atom is methylated. Reaction of [Me{2}Al{RNS-(Me)NR}]{2} with HgCl{2} or SnCl{2} results
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