Reactions of dinuclear metal carbonyl α-diimine complexes with alkynes. Part 2. Selective coupling of an a-diimine ligand and Co and Methyl propynoate molecules to give Fe2(CO)n{(R)N=C(H)C(H)N(R)C(O)C(H)=CC9O)OMe}, containing a flyover-type ligand and showing a reversible CO-induced metal-metal bond fission with X-ray crystal structures (n = 5, R = i-Pr; n = 6, R = c-Hex)

Koten, G. van; Muller, F.; Vrieze, K.; Heijdenrijk, D.

Reactions of dinuclear metal carbonyl α-diimine complexes with alkynes. Part 2. Selective coupling of an a-diimine ligand and Co and Methyl propynoate molecules to give Fe2(CO)n{(R)N=C(H)C(H)N(R)C(O)C(H)=CC9O)OMe}, containing a flyover-type ligand and showing a reversible CO-induced metal-metal bond fission with X-ray crystal structures (n = 5, R = i-Pr; n = 6, R = c-Hex)

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Reactions of dinuclear metal carbonyl α-diimine complexes with alkynes. Part 2. Selective coupling of an a-diimine ligand and Co and Methyl propynoate molecules to give Fe2(CO)n{(R)N=C(H)C(H)N(R)C(O)C(H)=CC9O)OMe}, containing a flyover-type ligand and showing a reversible CO-induced metal-metal bond fission with X-ray crystal structures (n = 5, R = i-Pr; n = 6, R = c-Hex)

Koten, G. van; Muller, F.; Vrieze, K.; Heijdenrijk, D.

(1989) Organometallics, volume 8, issue 1, pp. 33 - 40

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ISSN: 0276-7333

Publisher: American Chemical Society

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