Abstract
The reactions of bis[8-(dimethylamino)-1-naphthyl]tin(II) with dibromine or diiodine afford bis[8-(dimethylamino)-1-naphthyl]tin(IV) dibromide (1) and bis[8-(dimethylamino)-1-naphthyl]tin(IV) diiodide (2), respectively. Reaction of {2,6-[bis(dimethylamino)methyl]phenyl}(4-tolyl)tin(II) with diiodine gives {2,6-[bis(dimethylamino)Methyphenyl}(4-tolyl)tin(IV) diiodide (3) in quantitative yield. The crystal structures of 1 and 3 have been determined by X-ray diffraction methods. As a result of intramolecular coordination of
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