Abstract
The reactions of C~~-[(~-M~~NCo~btHain~edC fHrom~ )[P~tCP12~(S~Et2])2,a] n d [(2-MeJW6H4CH2)Li(TMEDA)] (TMEDA
= tetramethylethylenediamine), and of cis-[( 2-Me2NCH2C6H4)2Pt1w1]i th Hg11(02CR)2( R = Me, i-Pr) yielded a novel
type of cyclometalated Pt-Hg compound [(N-C)2(RCOJPtHg(02CR)] (N-C = 2-Me@C6H4CH2- and 2-Me$JCH2C6H4-).
An X-ray crystallographic study defined the molecular structure of [(2-Me2NCH2C6H,)2(r-MeC02)PtHg(02TChMee )].
pertinent crystal data are as follows: orthorhombic,
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