Novel Aryltitanium(IV) complexes containing h3-NCN-pseudofacial- and h3-NCN-meridional-bonded [C6H3(CH2NMe2)2-2,6]- (abbreviated as NCN) ligands. The crystal structures of [TiCl2(h3-fac-NCN)(O-i-Pr)], [TiCl(h3-mer-NCN)(O-i-Pr)(OTf)] containing an h1-O-bonded triflate anion and the seven-coordinated [Ti(h3-mer-NCN)(O-i-Pr)(OTf)2] containing h1-O- and h3-O,O'-bonded triflate anions

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