Abstract
The synthesis and characterization of new, five-coordinate molybdenum bis(imido) chloride complexes [MoCl(NCN)(N-t-Bu)2] (2) and [MoCl(2-C,N-NCN)(NAr)2] (3) and the methylated derivative [Mo(2-C,N-NCN)(Me)(NAr)2] (5) (NCN = [C6H3(CH2NMe2)2-2,6]-, Ar = C6H3-i-Pr2-2,6) are reported. Compounds 3 and 5 react with HCl to yield the corresponding air-stable salts [MoCl2{C6H3(CH2NMe2)-2-(CH2NHMe2)-6}(NAr)2] (4) and [MoCl{C6H3(CH2NMe2)-2-(CH2NHMe2)-6}(Me)(NAr)2] (6), respectively, of
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