Intramolecular rearrangements of sulfines coordinated to platinum. A unique equilibrium between oxidative-addition stereoisomers cis-(E)- and cis-(Z)-bis(triphenyl-phosphine) (methylthio)(arylsulfine)platinum(II) and the two stereoisomers of the reductive coupling product. Bis(triphenylphosphine) [aryl(methylthio)sulfine]platinum(0). Crystal and molecular structure of bis(triphenylphosphine)(9-sulfinylfluorene)platinum(0)-0.5-bezene

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