Abstract
Arylindium compounds of the type ArJnCl and ArMezIn, in which the Ar group is either 2-Me2NCHzC6H4
or (S)-2-Me2NCH(Me)C6H4, have been synthesized by the organolithium route and characterized by 'H
and 13C NMR spectroscopy. The NMR results clearly reveal that intramolecular In-N coordination occurs
in solution, resulting in fivecoordinate ArzInCl and four-coordinate ArMezIn structures.
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