Abstract
Square-planar iridium(I) complexes [Ir(C{6}H{4}CH{2}NRR')(cod)] (R = R' = Et; R = Me, R' = t-Bu; cod = cycloocta-1, 5-diene) containing C,N-chelating arylamine ligands have been synthesized and characterized by NMR spectroscopy. An X-ray diffraction study of [Ir(C{6}H{4}CH{2}NEt{2}-2-C,N)(cod)] shows a weak agostic interaction between the d}8{ metal center and a methyl
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