Abstract
New mono- and dinuclear aryltrialkylsilanes and -stannanes [Me3M{C6H3(CH2NMe2)2-2,6}] (M = Si (5), Sn (6)) and [(Me3M)2-1,4-{C6(CH2NMe2)4-2,3,5,6}] (M = Si (9), Sn (10)) have been prepared from transmetalation reactions of dimeric [Li{C6H3(CH2NMe2)2-2,6}]2 and new polymeric [Li2-1,4-{C6(CH2NMe2)4-2,3,5,6}] with (trimethylsilyl)trifluoromethanesulfonate or trimethyltin chloride. The X-ray crystal structures of dinuclear 9 and 10 have
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