Abstract
The water-soluble ionic aryl platinum species [Pt{C{6}H{3}(CH{2}NMe{2})-2, 6} (OH{2})]}+{ undergoes water exchange at a rate 10}7{ times faster than the coordination complex [Pt(OH{2}){4}]}2{}+{; a clear-cut example of the trans effect of the C-bonded organic group. Lineshape analysis of high pressure }1{}7{O NMR data acquired in a 14.1 tesla magnet are
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