Abstract
The organoplatinum(II) compounds [{2, 6-(Me{2}NCH{2}){2}C{6}H{3}}PtBr] and cis-[(C-N){2}Pt] (C-N = 2-Me{2}NCH{2}C{6}H{4}, 2-Me{2}NC{6}H{4}CH{2}) can be chemically irreversibly oxidized in the potential range 1.00 to 1.35 V vs. an Ag/AgCl electrode, whereas the organoplatinum@?mercury complexes [{2,6-Me{2}NCH{2}){2}C{6}H{3}}(RCO{2})PtHg(O{2}CR)Br] and [(C-N){2}@m-O,O'-RCO{2})PtHg(O{2}CR)] (R = Me) could only be reduced, in the potential range -0.20 to -0.70 V,
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