Abstract
The reaction of P,N-ligated dimethylpalladium(II) complexes [Pd(Me)2(P~N)] [P~N = o-(diphenylphosphino)-N,N-dimethylbenzylamine (PCN), (diphenylphosphino)-N,N-dimethylethyleneamine (PN)] with an equimolar amount of HOCH(CF3)2 or HOC6H4-4-X (X = H, Cl, OMe, Me, CN, NO2, OH) affords methylpalladium(II) alkoxide and aryl oxide complexes [Pd(Me)(OR)(P~N)] [R = CH(CF3)2, C6H4-4-X; P~N = PCN, PN], which have been isolated
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