Abstract
Mn(CO){5}M'(CO){3}DAB complexes (M' = Mn, Re; DAB = R{1}N=C(R{2})-C(R'{2})=NR{1}) can be easily obtained from the reaction between Mn(CO){5}}-{ and M'(CO){3}X(DAB) (M' = Mn, Re; X = Cl, Br, I). The complexes are formed by a nucleophilic mechanism, while a redistribution is responsible for the formation of a small amount of
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