Abstract
A study has been made of reactions involving organometallic compounds containing ortho-Me{2}NCH{2} substituted aryl ligands. The single step syntheses of the new compounds [(2-Me{2}NCH{2}C{6}H{4}){2}TlCl], [ [{(S)-2-Me{2}NCH(Me)C{6}H{4}}{2}TlCl], [{(S)-2-Me{2}NCH(Me)C{6}H{4}}TlCl{2}], [{2, 6-(Me{2}NCH{2}){2}C{6}H{3}}TlClBr] and [{2,6-(Me{2}NCH{2}){2}C{6}H{3}}HgCl] are described. Stable internal N@?Tl coordination at low temperatures has been established for the C-chiral thallium compounds. Reactions of
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