Abstract
Reaction of [TiCl{3}(O-i-Pr)] with [Li(CNN)]{2} (CNN = monoanionic C{6}H{4}(CH{2}N(Me)CH{2}CH{2}NMe{2})-2) in 2:1 molar ratio in toluene at -78}o{C afforded [TiCl{2}(CNN)(O-i-Pr)] as a 3:2 molar mixture of two stereoisomers. The stereoisomers differ by the mutual position of the chloro and alkoxy ligands. Molecular modelling calculations and an X-ray analysis of one of
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