Activation of an aliphatic C-H bond at room temperature. Conversion on a cluster of a stable s-bonded alkyl group to a m2-alkylidene ligand. Synthesis and crystal structure determination of HOs3(6-CH2C5H3N-2-C(H)=N-i-Pr)(CO)9 andH2Os3(6-CH-C5H3N-2-C(H)=N-i-Pr)(CO)8

Koten, G. van; Zoet, R.; Vrieze, K.; Jansen, J.; Goubitz, K.; Stam, C.H.

Activation of an aliphatic C-H bond at room temperature. Conversion on a cluster of a stable s-bonded alkyl group to a m2-alkylidene ligand. Synthesis and crystal structure determination of HOs3(6-CH2C5H3N-2-C(H)=N-i-Pr)(CO)9 andH2Os3(6-CH-C5H3N-2-C(H)=N-i-Pr)(CO)8

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Activation of an aliphatic C-H bond at room temperature. Conversion on a cluster of a stable s-bonded alkyl group to a m2-alkylidene ligand. Synthesis and crystal structure determination of HOs3(6-CH2C5H3N-2-C(H)=N-i-Pr)(CO)9 andH2Os3(6-CH-C5H3N-2-C(H)=N-i-Pr)(CO)8

Koten, G. van; Zoet, R.; Vrieze, K.; Jansen, J.; Goubitz, K.; Stam, C.H.

(1988) Organometallics, volume 7, issue 7, pp. 1565 - 1572

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ISSN: 0276-7333

Publisher: American Chemical Society

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