Abstract
Research on the chemistry and structural aspects of ortho-substituted-arylcopper and -cuprate compounds in which the ortho-substituents either interfere sterically with the C{i}{p}{s}{o}-to-copper bonding or have a potentially coordinating heteroatom, is described. Concluded is that the simple arylcopper and ortho-ligand substituted arylcopper compounds have many similar structural features. However, the self-complexed
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