A Novel Aryllithium : Lithium Bromide Complex Containing an Anionic Pentadentate Organylpolyamine System Enfolding two Lithium Centers

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A Novel Aryllithium : Lithium Bromide Complex Containing an Anionic Pentadentate Organylpolyamine System Enfolding two Lithium Centers
 
Koten, G. van; Wehman-Ooyevaar, I.C.M.; Kapteijn, G.M.; Grove, D.M.; Spek, A.L.
(1993) Journal of organometallic chemistry, volume 452, issue 1-2, pp. 1 - 3
(Article)
Abstract
The aryllithium compound Li2[C6H3CH2N(Me)CH2CH2NMe22 2,6]Br, which has been characterized by an X-ray crystallographic determination and by NMR spectroscopy, was obtained from the reaction of [C6H3Br(CH2N(Me)CH2CH2NMe2)2-2,6] with 2 equivalents of nBuLi. The lithium compound has a novel structural feature: a Li2ArBr core in which the bromide is bridge-bonded (LiBrLiŒ 64.8(2)‹) and ... read more
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DOI: https://doi.org/10.1016/0022-328X(93)83205-A
ISSN: 0022-328x
Publisher: Elsevier
 
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