Abstract
A Longoni-Chini cluster, [Ptl5(C0),l2-, was prepared on MgO powder by a surfacemediated synthesis from Na2PtCb
in the presence of CO. The formation of [Pt15(CO)30]2a-n d its decarbonylation at 120 'C under vacuum were characterized
by infrared and X-ray absorption spectroscopies. The decarbonylated cluster had an average Pt-Pt bond distance of 2.76
A and
... read more