Abstract
Sulfonamido−phosphoramidite ligands lead to the formation of Rh−Rh dinuclear complexes through the anionic P−N− bridging character. The resulting “boat-shaped” dinuclear catalysts activate molecular H2 through a cooperative dinuclear endocyclic mechanism, resulting in one bridging and one classical hydride on the dinuclear complex. These new complexes are very active hydrogenation catalysts
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