Abstract
Palladium nanoparticles of similar size of ~2 nm were synthesized on different silica-based materials, all functionalized with thiol groups i.e., Aerosil-380, SBA-15, plugged SBA-15 and m-MCF. The resulting materials were used to study the influence of the confinement of Pd nanoparticles in a functionalized silica support on the Heck and
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