A Well‐Defined Anionic Dicopper(I) Monohydride Complex that Reacts like a Cluster**

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A Well‐Defined Anionic Dicopper(I) Monohydride Complex that Reacts like a Cluster**
 
Bienenmann, Roel L. M.; Schanz, Alexandra J.; Ooms, Pascale L.; Lutz, Martin; Broere, Daniël L. J.
(2022) Angewandte Chemie-International Edition, volume 61, issue 29
(Article)
Abstract
Low-nuclearity copper hydrides are rare and few well-defined dicopper hydrides have been reported. Herein, we describe the first example of a structurally characterized anionic dicopper hydride complex. This complex does not display typical reactivity associated with low-nuclearity copper hydrides, such as alcoholysis or insertion reactions. Instead, its stoichiometric and catalytic ... read more
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Keywords: Copper Hydrides, Dinuclear Complexes, Expanded Pincer, Homogeneous Catalysis, Hydrosilylation, Catalysis, General Chemistry
DOI: https://doi.org/10.1002/anie.202202318
ISSN: 1433-7851
Publisher: John Wiley and Sons Ltd
Note: Funding Information: This work was supported by The Netherlands Organization for Scientic Research (VI.Veni.192.074 to D.L.J.B.). Access to supercomputer facilities was sponsored by NWO Exacte en Natuurwetenschappen (Physical Sciences). Bert Klein-Gebbink and Marc-Etienne Moret are acknowledged for valuable discussions and suggestions. The X-ray diffractometer was financed by the NWO. We would like to thank Emily Monkcom for the beautifully designed TOC graphic. Funding Information: This work was supported by The Netherlands Organization for Scientic Research (VI.Veni.192.074 to D.L.J.B.). Access to supercomputer facilities was sponsored by NWO Publisher Copyright: © 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.
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