A phosphorus analogue of Bis(η4-cyclobutadiene)iron(0)

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A phosphorus analogue of Bis(η4-cyclobutadiene)iron(0)
 
Wolf, Robert; Slootweg, J.C.; Ehlers, A.W.; Hartl, F.; de Bruin, B.; Lutz, M.; Spek, A.L.; Lammertsma, K.
(2009) Angewandte Chemie-International Edition, volume 48, issue 17, pp. 3104 - 3107
(Article)
Abstract
P makes it possible: the convenient oxidative synthesis of the 16-electron organophosphorus iron sandwich complex [Fe(4-P2C2tBu2)2] (see structure) suggests that the elusive all-carbon complex [Fe(4-C4H4)2] is a viable synthetic target.
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ISSN: 1433-7851
Publisher: John Wiley and Sons Ltd
(Peer reviewed)
 
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