Chiral rhodium(II) carboxamides. A new class of catalysts for enantioselective cyclopropanation reactions

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Chiral rhodium(II) carboxamides. A new class of catalysts for enantioselective cyclopropanation reactions
 
Doyle, M.P.; Brandes, B.D.; Kazala, A.P.; Pieters, R.J.; Jarstfer, M.B.; Watkins, L.M.; Eagle, C.T.
(1990) Tetrahedron Letters, volume 31, issue 46, pp. 6613 - 6616
(Article)
Abstract
Chiral Rh2L4 (L = 4-substituted-oxalidinones and methyl 2-pyrrolidone-5-carboxylate) having two nitrogen-rhodium bonds in the cis geometry at each rhodium face are effective catalysts for enantioselective intermolecular cyclopropanation reactions.
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Keywords: cyclopropane derivative, rhodium, article, catalysis, methodology, nonhuman, priority journal, synthesis
DOI: https://doi.org/10.1016/S0040-4039(00)97128-4
ISSN: 0040-4039
Publisher: Elsevier
(Peer reviewed)
 
 
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