Crystal structure of tetra­kis­(tetra­hydro­furan-κO)bis­(tri­fluoro­methane­sulfonato-κO)iron(II)

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Crystal structure of tetra­kis­(tetra­hydro­furan-κO)bis­(tri­fluoro­methane­sulfonato-κO)iron(II)
 
Riemersma, Charl F.; Monkcom, Emily C.; Klein Gebbink, Robertus J. M.; Lutz, Martin
(2019) Acta Crystallographica Section E Crystallographic Communications, volume 75, issue 10, pp. 1548 - 1551
(Article)
Abstract
The title compound, [Fe(CF3SO3)2(C4H8O)4], is octa­hedral with two tri­fluoro­methane­sulfonate ligands in trans positions and four tetra­hydro­furane mol­ecules in the equatorial plane. By the conformation of the ligands the complex is chiral in the crystal packing. The compound crystallizes in the Sohncke space group P212121 and is enanti­omerically pure. The packing ... read more
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Keywords: crystal structure, high-spin iron(II), split-mosaic model
DOI: https://doi.org/10.1107/S2056989019013094
ISSN: 2056-9890
Publisher: International Union of Crystallography
(Peer reviewed)
 
 
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