Cobalt(II) and (I) Complexes of Diphosphine-Ketone Ligands: Catalytic Activity in Hydrosilylation Reactions

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Cobalt(II) and (I) Complexes of Diphosphine-Ketone Ligands: Catalytic Activity in Hydrosilylation Reactions
 
Verhoeven, Dide G. A.; Kwakernaak, Joost; Van Wiggen, Maxime A. C.; Lutz, Martin; Moret, Marc-Etienne
(2019) European Journal of Inorganic Chemistry, volume 2019, issue 5, pp. 660 - 667
(Article)
Abstract
The catalytic activity of cobalt(II) and cobalt(I) complexes of the diphosphine ketone ligand pToldpbp is demonstrated in the hydrosilylation of 1‐octene with phenylsilane under mild conditions, showing the first catalytic application of dpbp ligands in combination with base metals.
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Keywords: Silane chemistry, Cobalt, Hydrosilylation, Homogeneous catalysis, Cooperative catalysis
DOI: https://doi.org/10.1002/ejic.201801221
ISSN: 1434-1948
Publisher: Wiley-VCH Verlag
(Peer reviewed)
 
 
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