A Direct Catalytic Synthesis of Sodium Diarylphosphinates and Their Corresponding Acids from Sodium Phosphinate

DSpace/Manakin Repository

A Direct Catalytic Synthesis of Sodium Diarylphosphinates and Their Corresponding Acids from Sodium Phosphinate
 
Botez, Laurian; de Jong, G. Bas; Slootweg, J. Chris; Deelman, Berth Jan
(2017) European Journal of Organic Chemistry, volume 2017, issue 3, pp. 434 - 437
(Article)
Abstract
In this contribution we present the direct conversion of sodium phosphinate (NaH2PO2·H2O) to symmetrical sodium diarylphosphinates and their corresponding acids by using palladium catalysis. This route eliminates the need for chlorinated precursors, such as PCl3 and intermediate alkyl- or ammoniumphosphinates.
Download/Full Text
The full text of this publication is not available.
 
Keywords: Cross-coupling, Homogeneous catalysis, Industrial chemistry, Palladium, Phosphinates, Sustainable chemistry, Physical and Theoretical Chemistry, Organic Chemistry
DOI: https://doi.org/10.1002/ejoc.201601222
ISSN: 1434-193X
Publisher: Wiley-VCH Verlag
(Peer reviewed)
 
 
See more statistics about this item