A 3:1 site-differentiated [4Fe-4S] cluster immobilized on a self-assembled monolayer

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A 3:1 site-differentiated [4Fe-4S] cluster immobilized on a self-assembled monolayer
 
van der Geer, E.P.L.; van den Brom, C.R.; Arfaoui, I.; Houssiau, L.; Rudolf, P.; van Koten, G.; Klein Gebbink, R.J.M.; Hessen, B.
(2008) Journal of Physical Chemistry C, volume 112, issue 44, pp. 17225 - 17230
(Article)
Abstract
A 3:1 site-differentiated [4Fe-4S] cluster is immobilized on a thiol-functionalized self-assembled monolayer (SAM) on Au(111) by thiol−thiolate exchange chemistry. Fe 2p signals observed by X-ray photoelectron spectroscopy support the presence of [4Fe-4S] clusters at the SAM surface; further evidence comes from the detection of n-Bu4N+ and cluster-derived species by secondary-ion ... read more
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ISSN: 1932-7447
Publisher: American Chemical Society
(Peer reviewed)
 
 
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