Abstract
The use of 2,2′:6′,2″-terpyridine-4′-thiol (tpySH) was explored as a bridging ligand for the formation of stable assemblies containing both [4Fe−4S] clusters and single metal ions. Reaction of tpySH (2 equiv) with (NH4)2Fe(SO4)2·6H2O generated the homoleptic complex [Fe(tpySH)2]2+, which was isolated as its PF6− salt. The compound could be fully deprotonated
... read more