Electric-Field-Induced Lock-and-Key Interactions between Colloidal Spheres and Bowls

Abstract

To realize new and directed self-assembly (SA) pathways, the focus in colloid science and nanoscience has shifted from spherical particles and interactions to increasingly more complex shapes and interparticle potentials. This field is fueled by recent breakthroughs in particle synthesis, such as particles with complementary shapes that allow for specific lock-and-key interactions induced by depletants. Here, we show that electric fields form an alternative route for directing the SA of convex and concave colloids, with the additional advantage that the system now becomes switchable by external conditions. Both experimental and theoretical results are presented that validate the electric-field-induced assembly mechanism and show that even irreversibly bound composites can be generated by tuning the force balance. The successful isolation of the irreversible composite particles, in combination with generalization to different materials, shows that the current mechanism provides a versatile new path not only toward complex-particle synthesis but also toward directed self-assembly.