Preorganized Frustrated Lewis Pairs

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Preorganized Frustrated Lewis Pairs
 
Bertini, F.; Lyaskovskyy, V.; Timmer, B.J.J.; de Kanter, F.J.J.; Lutz, M.; Ehlers, A.W.; Slootweg, J.C.; Lammertsma, K.
(2012) Journal of the American Chemical Society, volume 134, pp. 201 - 204
(Article)
Abstract
Geminal frustrated Lewis pairs (FLPs) are expected to exhibit increased reactivity when the donor and acceptor sites are perfectly aligned. This is shown for reactions of the nonfluorinated FLP tBu2PCH2BPh2 with H2, CO2, and isocyanates and supported computationally.
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DOI: https://doi.org/10.1021/ja210214r
ISSN: 0002-7863
Publisher: American Chemical Society
(Peer reviewed)
 
 
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