Mechanism of olefin epoxidation by a mono-oxygenase model

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Mechanism of olefin epoxidation by a mono-oxygenase model
 
Nolte, R.J.M.; Razenberg, J.A.S.J.; Drenth, W.
(1984) Tetrahedron Letters, volume 25, issue 7, pp. 789 - 792
(Article)
Abstract
Kinetic data suggest that the rate determining step in the epoxidation of cyclohexene by Mn-TPP and sodium hypochlorite is the conversion of a Mn(III)-species into an oxo-manganese(V)-species.
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ISSN: 0040-4039
Publisher: Elsevier
 
 
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