Highly fluorous zirconocene(IV) complexes and their catalytic applications in the

Cámpora, J.; Matas, I.; Palma, P.; Álvarez, E.; Kleijn, H.; Deelman, B.J.; Passaglia, E.

doi:https://doi.org/10.1016/j.jorganchem.2010.03.030

Highly fluorous zirconocene(IV) complexes and their catalytic applications in the

DSpace/Manakin Repository

Highly fluorous zirconocene(IV) complexes and their catalytic applications in the

Cámpora, J.; Matas, I.; Palma, P.; Álvarez, E.; Kleijn, H.; Deelman, B.J.; Passaglia, E.

(2010) Journal of Organometallic Chemistry, volume 695, issue 14, pp. 1794 - 1800

(Article)

Abstract

The catalytic activities of the highly fluorous systems formed by the zirconocene(IV) complexes [Zr{h5- C5H4SiMe2C2H4RF}2Cl2] (RF ¼ C6F13 (4a), C10F21 (4b)) or [Zr-{h5-C5H3(SiMe2C2H4C6F13)2}2Cl2] (5a) and MMAO in toluene have been studied and compared with analogous nonfluorous systems generated from [Zr{h5-C5H4SiMe3}2Cl2] and [Zr{h5-C5H5}2Cl2]. Although less active than the reference systems, the ... read more

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DOI: https://doi.org/10.1016/j.jorganchem.2010.03.030

ISSN: 0022-328X

Publisher: Elsevier

(Peer reviewed)

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