Abstract
The pyramidalizations of N9/1 glycosidic nitrogens in DNA and RNA nucleosides, recently discovered and analyzed in their ultrahigh-resolution X-ray crystal structures (Sychrovsky´; et al. Nucleic Acid Res. 2009, 37, 7321.), were found to have significant effects on the structural interpretation of the 3J(C4/2-H1′) and 3J(C8/ 6-H1′) NMR scalar couplings in
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