Controlled Assemly of a Heterogeneous Single-Site Ethylene Trimerization Catalyst as Probed by X-ray Absorption Spectroscopy

Abstract

X-ray absorption spectroscopy at the Cr K and L₂,₃-edges was used to study the assembling process of a heterogeneous Cr-based single-site catalyst. The starting point was a Phillips-type system with monochromate species anchored on a silica surface, which was first reduced to a variety of different surface Cr¹¹ species. The reduced sample was modified with a 1,3,5-tribenzylhexahydro 1,3,5-triazine (TAC) ligand in the presence of CH₂Cl₂ as solvent to yield a heterogeneous single-site Cr-based catalyst active in the trimerization of ethylene. The molecular structure of the resultant catalytic material consists of distorted octahedral Cr¹¹¹ species. The extended X-ray absorption fine-structure (EXAFS) spectroscopy fitting procedure in R space up to 2.5 A showed that the synthesis leads to coordination with a TAC ligand. The fit also shows that it was possible to complete the six-fold environment around C¹¹¹ with two oxygen atoms and one chloride ligand. This chloride ligand is formed in a redox process from the solvent and is responsible for the oxidation of surface Cr¹¹ to Cr¹¹¹. The obtained geometry and the local environment of the surface complex are discussed in light of its homogeneous counterpart and confirm the single-site characteristics of the prepared catalytic material.