Abstract
The theory of faradaic rectification polarography is extended to systems of higher order stoichiometry. The couples Zn2+/Zn(Hg) in 0.5 M MgSO4 and Cd2+/Cd(Hg) in 1 M KCl are studied with the aid of this technique in a wide potential range. The Zn2+/Zn reaction is interpreted as a multistep mechanism. The
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