Investigations on organolead compounds III. The reaction of organolead compounds with ketene. (Triphenylplumbyl)acetic anhydride

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Investigations on organolead compounds III. The reaction of organolead compounds with ketene. (Triphenylplumbyl)acetic anhydride
 
Willemsens, L.C.; Kerk, G.J.M. van der
(1965) Journal of Organometallic Chemistry, volume 4, issue 3, pp. 241 - 244
(Article)
Abstract
The reaction of ketene with triphenyllead hydroxide in diethyl ether gave (triphenylplumbyl)acetic anhydride, (Ph3PbCH2CO)2O, the first anhydride-substituted organolead compound known. The reaction of ketene with triphenyllead acetate in absolute ethanol gave ethyl (triphenylplumbyl)acetate, Ph3PbCH2COOEt. A few reactions of the anhydride are described.
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ISSN: 0022-328X
Publisher: Elsevier
 
 
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