Abstract
The conclusions arrived at in Part 11 of this series have been verified experimentally with Cd2+/Cd(Hg) in M NaClO 4, Fe2+/Fe3+ in M oxalate and Cd2+/Cd(Hg) in M KCl. The numerical method leads to values of the rate constant ksh that agree with those obtained by graphical extrapolation only if
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