Telomerization of 1,3-butadiene with various alcohols by Pd/TOMPP catalysts: new opportunities for catalytic biomass valorization

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Telomerization of 1,3-butadiene with various alcohols by Pd/TOMPP catalysts: new opportunities for catalytic biomass valorization
 
Palkovits, Regina; Parvulescu, Andrei N.; Hausoul, Peter J. C.; Kruithof, Cornelis A.; Gebbink, Robertus J. M. Klein; Weckhuysen, Bert M.
(2009) Green Chemistry, volume 11, issue 8, pp. 1155 - 1160
(Article)
Abstract
The telomerization of 1,3-butadiene with various alcohols has been investigated using a catalyst based on a Pd(acac)(2) precursor and a phosphine ligand, TOMPP (TOMPP = tris-(o-methoxyphenyl)phosphine). We were able to demonstrate the capability of the catalyst to telomerize 1,3-butadiene with various multifunctional nucleophiles having primary and secondary alcohol functions. High ... read more
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Keywords: Palladium catalysts, Convenient route, Fine chemicals, Butadiene, Efficient, Glycerol, Sucrose, Ligands, Hydrogenation, Dimerization, International (English)
DOI: https://doi.org/10.1039/b904274a
ISSN: 1463-9262
Publisher: Royal Society of Chemistry
(Peer reviewed)
 
 
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