Abstract
The first crystal structures of lipases that have been covalently modified through site-selective inhibition by different organometallic phosphonatepincer– metal complexes are described. Two ECE-pincer-type d8-metal complexes, that is, platinum (1) or palladium (2) with phosphonate esters (ECE=[(EtO)-(O=)PACHTUNGTRENUNG(-O-C6H4-ACHTUNGTRENUNG(NO2)- 4)ACHTUNGTRENUNG(-C3H6-4-ACHTUNGTRENUNG(C6H2-ACHTUNGTRENUNG(CH2E)2)] ; E= NMe2 or SMe) were introduced prior to crystallization and have
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