Hexanuclear [Ni6L12] metallacrown framework consisting of NiS4 square-planar and NiS5 square-pyramidal building blocks

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Hexanuclear [Ni6L12] metallacrown framework consisting of NiS4 square-planar and NiS5 square-pyramidal building blocks
 
Angamuthu, R.; Kooijman, H.; Lutz, M.; Spek, A.L.; Bouwman, E.
(2007) Journal of the Chemical Society. Dalton transactions : inorganic chemistry, pp. 4641 - 4643
(Article)
Abstract
The hexanuclear [Ni6L12] (2) wheel-type cluster adopts an unusual structural motif whereby four NiS4 square-planar and two NiS5 square-pyramidal units are conjoined by edge sharing; the NiS5 units resemble the Ni centre of the inactive state in the [NiFe] hydrogenase.
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ISSN: 0300-9246
(Peer reviewed)
 
 
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