2-(2′-Pyridyl)-4,6-diphenylphosphinine versus 2-(2′-pyridyl)-4, 6-diphenylpyridine: An evaluation of their coordination chemistry towards Rh(i)

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2-(2′-Pyridyl)-4,6-diphenylphosphinine versus 2-(2′-pyridyl)-4, 6-diphenylpyridine: An evaluation of their coordination chemistry towards Rh(i)
 
Campos Carrasco, A.; Pidko, E.A.; Masdeu-Bultó, A. M.; Lutz, M.; Spek, A.L.; Vogt, D.; Müller, C.
(2010) New Journal of Chemistry, volume 34, issue 8, pp. 1547 - 1550
(Article)
Abstract
The coordination chemistry of the bidentate P,N hybrid ligand 2-(2′-pyridyl)-4,6-diphenylphosphinine towards Rh(I) has been investigated and compared to the structurally analogous 2,2′-bipyridine derivative. Considerable differences in the molecular structures of the mononuclear [Rh(cod)L2]BF4 complexes were observed and attributed to the different steric and electronic properties of functionalized phosphinines compared to ... read more
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DOI: https://doi.org/10.1039/c0nj00030b
ISSN: 1369-9261
Publisher: Royal Society of Chemistry
(Peer reviewed)
 
 
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